Step 1:
\Total mass of the mixture is 20 g.
\Freezing point of the solution is
.
At ideal conditions:
\Total mass of mixture =Mass of sucrose + Mass of the 
Let mass of the sucrose be
grams.
Molar Mass of the sucrose is 324.496 g/mol
\Amount of sucrose in moles is
\
Mass of
is
grams.
Molar Mass of the
is 58.44 g/mol

Mass of the solute = Mass of the solvent + Mass of the solution.
\
.
Step 2:
\Freezing point of water
, where
is the change in temperature and
,
is the van t Hoff factor,
is the molality of the solution and
is the molality depression constant =
.
Freezing point : 

Here
for sucrose is 1.
for sodium chloride is 2.
Substitute 

Mass of the sucrose is 14.55 g.
\Mass of the sodium chloride is 20-14.55 = 5.45 g.
\Step 3:
\Mass percentage of the substance is
.
Mass percentage of Sucrose:
\
Mass percentage of Sodium chloride:
\
Mole fraction of substance is 
Mole fraction of sucrose:
\
Solution:
\Mass percentage of Sucrose is 72.8%
\Mass percentage of Sodium chloride is 27.25%
\Mole fraction of sucrose is 0.343.