\
Consider the side of the square box be
.
The height of the box be
.
The surface area of the square box with open top is
.
But area of the box is
cm2.

The volume of the box is
.

Volume of the square box is maximum when its first derivative becomes zero.
\Apply derivative on each side with respect to
.

.
\
Equate
to zero.

The side of the square base is
.
Substitute
in
.

Therefore the volume of the box has a maximum value is
.
\
The volume of the box has a maximum value is
.